How can you change the network binding order of network interfaces on a Windows installation that doesn't have a GUI like Windows Server Core? You'll need a special tool called nvspbind for doing this, which allows for modifying network bindings from the command line.
You can download nvspbind from here:
Mitch Tulloch is a seven-time recipient of the Microsoft Most Valuable Professional (MVP) award and widely recognized expert on Windows administration, deployment and virtualization. For more tips by Mitch you can follow him on Twitter or friend him on Facebook.